Electron Affinity of Element 114, with Comparison to Sn and Pb

نویسندگان

  • A. Borschevsky
  • V. Pershina
  • U. Kaldor
چکیده

Knowledge of the electronic structure and properties of element 114 is important for its chemical identification. By comparing its behaviour with that of the lighter group 14 homologues, its position in the periodic table can be confirmed. In this work, we investigate the electron affinity (EA) of element 114, together with its lighter homologues in group 14, Sn and Pb [1]. Electron affinity is important for calculations of chemical potential, μ, and electronegativity, χ, which, in turn, reflect chemical reactivity of the element under study. The calculations were performed in the framework of the projected Dirac-Coulomb-Breit Hamiltonian,

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

CYCLIC POTENTIODYNAMIC POLARIZATION STUDY OF TERNARY PB -SN-CA ALLOY IN 2M H_2SO_4 SOLUTION

In this paper redox reaction processes and phase, formation on ternary Pb-2Sn-0.08Ca alloy utilized as insoluble lead anodes in copper electro winning cells, were investigated in 2M H__2SO__4 electrolytes, using cyclic voltammetry technique (CVA). A potential range between - 1.3V to 2.6V was chosen at various scan rates in order to study the anodic behavior and phase composition of the oxide la...

متن کامل

Prediction of the Adsorption Behaviour of Pb and Element 114 on Inert Surfaces from ab initio Dirac-Coulomb Atomic Calculations

For the chemical identification of the heaviest elements, like 112 and 114, which are of current interest, predictions of their adsorption behaviour on various surfaces used in the experiments are essential. Recently, we have predicted adsorption of element 114 and its homolog Pb on metal surfaces on the basis of the fully relativistic density functional theory calculations of intermetallic com...

متن کامل

استفاده از روش‌های آمار انفصال و تحلیل‌های عاملی و خوشه‌ای برای بررسی رفتار زمین-شیمیایی نقره در کانی‌زایی مس-مولیبدن پورفیری حراران، استان کرمان

One of the silver resources is Cu-Mo porphyry deposits, producing silver as by product. For this research, the results of analysis of 607 lithogeochemical samples for W, Zn, Ag, As, Ba, Co, Cu, Mo, Pb, Sb, Sn, Sr, Bi  elements were used to investigate geochemical behavior of silver element in Hararan area which is located in the southeast of Iran and consists of copper mineralization seems to b...

متن کامل

Assessment of the Radiation Attenuation Properties of Several Lead Free Composites by Monte Carlo Simulation

Background:In diagnostic radiology lead apron, are usually used to protect patients and radiology staff against ionizing radiation. Lead apron is a desirable shield due to high absorption and effective attenuation of x-ray photons in the diagnostic radiology range.Objective: Although lead aprons have good radiation protection properties, in recent years, researchers have been looking for altern...

متن کامل

Test method for the presence or absence of Pb in electrical components using energy-dispersive micro X-ray fluorescence.

The micro-EDXRF (energy dispersive X-ray fluorescence) method was applied to the screening of Pb in micrometer-area samples, such as a Cu contact in electrical components that had been coated by Pb-free Sn-Ag-Cu solder. The reliability of the screening method was evaluated by a comparison with a scanning electron microscope (SEM) observation and a precious chemical analysis method of inductivel...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2010